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MATCHING MATCH a structure or term from the following list with each description below. Place the letter of the structure or term in the blank to the left of the description. -______ Groups which activate aromatic rings towards electrophilic substitution.


A) benzyne
B) "+NO2"
C) R3C+
D) electron-donating
E) "+NO"
F) Meisenheimer complex
G) MATCHING MATCH a structure or term from the following list with each description below. Place the letter of the structure or term in the blank to the left of the description. -______ Groups which activate aromatic rings towards electrophilic substitution. A) benzyne B)  <sup>+</sup>NO<sub>2</sub>  C) R<sub>3</sub>C<sup>+</sup> D) electron-donating E)  <sup>+</sup>NO  F) Meisenheimer complex G)   H) electron-withdrawing
H) electron-withdrawing

I) G) and H)
J) A) and G)

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Which of the following is the reactive intermediate in the nucleophilic substitution of 4-bromo-1-nitrobenzene with sodium hydroxide? Which of the following is the reactive intermediate in the nucleophilic substitution of 4-bromo-1-nitrobenzene with sodium hydroxide?   A) 1 B) 2 C) 3 D) 4


A) 1
B) 2
C) 3
D) 4

E) A) and B)
F) All of the above

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Provide the structure (a single resonance contributor) of the key intermediate in the electrophilic aromatic chlorination of nitrobenzene. Provide the structure (a single resonance contributor) of the key intermediate in the electrophilic aromatic chlorination of nitrobenzene.

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Consider the reaction below to answer the following question(s) . Consider the reaction below to answer the following question(s) .   Fill in the blank with the appropriate letter or response. -The nucleophile in the reaction is _____. A) A B) B C) C D) D Fill in the blank with the appropriate letter or response. -The nucleophile in the reaction is _____.


A) A
B) B
C) C
D) D

E) A) and C)
F) A) and B)

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Which of the following sets of substituents are all activating groups in electrophilic aromatic substitution reactions?


A) CH3, OCH3, COCH3
B) Cl, CN, NO2
C) Cl, NH2, CH3
D) CH3, NH2, OCH3

E) B) and D)
F) All of the above

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What is the major organic product obtained from the following reaction? What is the major organic product obtained from the following reaction?   A) 1 B) 2 C) 3 D) 4


A) 1
B) 2
C) 3
D) 4

E) B) and D)
F) A) and B)

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What is the major organic product obtained from the following reaction (if a reaction is likely to give you a mixture of ortho and para disubstituted compounds you should assume that they can be separated; continue the synthesis with either one)? What is the major organic product obtained from the following reaction (if a reaction is likely to give you a mixture of ortho and para disubstituted compounds you should assume that they can be separated; continue the synthesis with either one)?

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